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Spider web-inspired gelatin-based bioplastic enables closed-loop recyclable, biodegradable, and sustainable packaging
DOI: 10.1039/D5GC02900G, PaperYuehong Zhang, Langlang Dai, Chen Yang, Bin Wei, Guangfu Liao
A spider web-inspired, glycerol-free gelatin bioplastic, engineered by integrating tea polyphenols (TP) and hyperbranched polyester (HBPE), enables closed-loop recyclable and biodegradable sustainable packaging.
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Enzyme immobilization advances: a key to unlocking renewable bioenergy potential
DOI: 10.1039/D5GC03388H, Critical Review
Open Access 
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Mohamed E. Hassan, Xuhai Zhu, Evanildo F. de Souza, Magdy M. Elnashar, Fang LuThis review provides an in-depth analysis of enzyme immobilization techniques and their application in catalyzing the transformation of biomass into high-value chemicals.
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Modulating the Cu (111) Facet for Selective CO2 Electroreduction via Tuning Polyaniline’s Oxidation State
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02285A, PaperYeqing Xu, Chong-Yong Lee, Yong Zhao, Yu Yang, Xin Wang, Zhiqi Chen, Klaudia Wagner, Wei Kong Pang, Gordon G. Wallace, Caiyun Wang
Polyaniline (PANI) can molecularly modify metal copper to enhance CO2 electrochemical reduction (CO2ECR) performance. It is widely accepted that PANI enhances the performance by interacting with CO2 molecules and intermediates...
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DOI: 10.1039/D5GC02285A, PaperYeqing Xu, Chong-Yong Lee, Yong Zhao, Yu Yang, Xin Wang, Zhiqi Chen, Klaudia Wagner, Wei Kong Pang, Gordon G. Wallace, Caiyun Wang
Polyaniline (PANI) can molecularly modify metal copper to enhance CO2 electrochemical reduction (CO2ECR) performance. It is widely accepted that PANI enhances the performance by interacting with CO2 molecules and intermediates...
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Technical and carbon footprint assessment of mortars derived from CO2 and magnesia recovered from bischofite
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03502C, PaperYufeng Song, Jiaze Wang, Jiahao Zhou, Xinpeng Wang, Cise Unluer, Tao Shi, Aoyun Zhang, Cheng-Gong Chang, Shaoqin Ruan
Bischofite (MgCl2·6H2O), the byproduct of salt lake resource extraction, is a useful source for valuable resources. This study investigated the production and utilization of reactive magnesia (MgO) cement (RMC) from...
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DOI: 10.1039/D5GC03502C, PaperYufeng Song, Jiaze Wang, Jiahao Zhou, Xinpeng Wang, Cise Unluer, Tao Shi, Aoyun Zhang, Cheng-Gong Chang, Shaoqin Ruan
Bischofite (MgCl2·6H2O), the byproduct of salt lake resource extraction, is a useful source for valuable resources. This study investigated the production and utilization of reactive magnesia (MgO) cement (RMC) from...
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A quasi-single-crystalline/amorphous high-entropy layered hydroxide for robust glycerol valorization to formate
DOI: 10.1039/D5GC03670D, PaperWenqian Zheng, Xianghui Pang, Changgang Dong, Liheng Sun, Jiaqi Guo, Pin Hao, Fengcai Lei, Xu Sun, Junfeng Xie
The glycerol oxidation reaction (GOR) offers a promising alternative to the oxygen evolution reaction in water electrolysis, enabling energy-saving hydrogen production and formate synthesis.
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Polyurethane depolymerization by dialkyl carbonates: toward sustainable chemical recycling
DOI: 10.1039/D5GC02533H, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ege Hosgor, Ricardo P. Martinho, Jip S. Hoogland, Yuqi Jia, Anahi Morales Gomez, Willem Verboom, Jean-Paul Lange, Jurriaan HuskensHarmless chemical recycling of polyurethane foams: depolymerization with diethyl carbonate allows deep recovery of both constituting monomers, i.e. polyols and diisocyanates, without requiring phosgene as toxic and wasteful reagent.
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Glycine/carbon quantum dot dual modulation cooperatively stabilizing Zn anode interfaces
DOI: 10.1039/D5GC03101J, PaperShuhua Yang, Zenglong Xu, Yiqun Du, Jinfeng Sun, Degang Zhao, Bingqiang Cao
Double-effect glycine (Gly)/carbon quantum dot (CQD) hybrid additives were designed to simultaneously regulate Zn2+ solvation sheath reconstruction and guide uniform Zn deposition, significantly enhancing Zn anode stability.
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Beyond bubbles: greener flow-based electroanalysis by an air-driven carrier
DOI: 10.1039/D5GC02382C, PaperTayná Silva Bernardino Barros, Eloise de Lima Osorio, Cláudio Teodoro de Carvalho, Raphael Rodrigues, Lucio Angnes, Magno Aparecido Gonçalves Trindade
An air-driven carrier for electrochemical system applications is developed as a novel approach to improve environmental sustainability in microfluidics devices.
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Electrochemically relevant physical–chemical properties of tetraalkylammonium salts solutions in the renewable solvent dihydrolevoglucosenone (Cyrene®); electrochemical behaviour of some representative organic molecules
DOI: 10.1039/D5GC03356J, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.José M. Ramos-Villaseñor, Jessica Sotelo-Gil, Maricarmen P. Flores-Morales, Ruben Vasquez-Medrano, Bernardo A. Frontana-UribeConductivity, viscosity, IR spectroscopy of tetraalkylammonium salts solutions in DLG, and the electrochemical behavior of representative molecules was studied.
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Molecular recognition interfaces driving homogeneous zinc deposition for superior Zn metal anodes
DOI: 10.1039/D5GC02826D, PaperFusheng Luo, Xin Qi, Qing Wu, Jinlong Zhang, Song Yang, Xiude Liu, Zeyu Yan, Jun Huang
RNA and DNA as eco-friendly electrolyte additives form stable nucleic acid recognition interfaces, protecting Zn anodes and promoting uniform interfacial reactions for high-performance ZIBs.
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Advances in lignocellulosic biomass pyrolysis and catalytic upgrading for sustainable biofuel production: process design strategies and reaction rationales
DOI: 10.1039/D5GC02199E, Critical ReviewPenghui Yan, Hong Peng, Hesamoddin Rabiee, Lei Ge, Yilun Weng, Beibei Ma, Juntao Wang, Muxina Konarova, Guangyu Zhao, Eric M. Kennedy, Zhonghua Zhu, Michael Stockenhuber
Biomass is converted into drop-in fuels via pyrolysis-hydrodeoxygenation or hydropyrolysis pathways, culminating in renewable energy solutions that support carbon neutrality.
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Self-initiated radical leaching for green recovery of precious metals
DOI: 10.1039/D5GC02561C, PaperChenchen Zhu, Anting Ding, Chuanyin Liu, Ming Li, Chengliang Xiao
A green, low-cost strategy using AlCl3 solution enables efficient recovery of Pd and Pt from spent catalysts via a self-initiated radical leaching process.
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Additively manufactured electrochemical platforms from reclaimed ground tire rubber for environmental monitoring
DOI: 10.1039/D5GC02259B, PaperGilvana P. Siqueira, Agata Rodak, Raquel G. Rocha, Tomasz Swebocki, Mateusz Cieślik, Eduardo M. Richter, Krzysztof Formela, Jacek Ryl, Rodrigo A. A. Muñoz
Reclaimed ground tire rubber enables the additive manufacturing of sensors for carbendazim sensing in water.
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Solvent-promoted catalyst-free aminolytic upcycling of waste polyethylene terephthalate under low-temperature conditions
DOI: 10.1039/D5GC02469B, CommunicationZan Yang, Meihua Chen, Anqi Huang, Jundong Xu, Congshan Zhou, Yongbing Yuan
A solvent-promoted catalyst-free aminolysis method for the chemical upcycling of waste polyethylene terephthalate was explored.
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Mechanochemical synthesis of tetramic acids and their biomimetic ring expansion to 4-hydroxy-2-pyridones
DOI: 10.1039/D5GC03085D, Communication
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kalliopi Mazaraki, Aimilia Eirini Tsirozidou, Basil Kakarikas, Alexandros L. ZografosRolling towards pyridones: ball milling enables green tetramic acid synthesis and its smooth biomimetic expansion to valuable heterocycles.
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Catalytic reductive conversion of polyethylene terephthalate (PET) plastic waste into fuels, valuable chemicals and degradable polymers
DOI: 10.1039/D5GC03083H, Tutorial ReviewJingyu Liu, Shuyan Yi, Jingwen Cheng, Sibao Liu
This review presents recent advancements in the catalytic reductive recycling and upcycling of PET into fuels, valuable chemicals and degradable polymers.
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An in situ phosphorization constructed VP2@VS2 nanoflower heterostructure with a modulated d-band center of V for efficient polysulfide adsorption and conversion in lithium–sulfur batteries
DOI: 10.1039/D5GC03028E, PaperZhidong Ye, Yaxiong He, Huasheng Gao, Heming Hu, Tao Chen, Qi Jiang
Li-S: low cost, high energy (≈2600 Wh kg−1), abundant S. VP2@VS2 enables triple synergy: LiPSs adsorption, d-band optimization, Li2S barrier reduction. 88% retention after 1000 cycles@2C, suppresses shuttle, enables renewable storage.
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Electrocatalytic hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran over POx modified Cu electrocatalysts: the promoting role of POx
DOI: 10.1039/D5GC02693H, PaperYiwei Zhao, Chao Zhang, Zuhang Jin, Cheng Tao, Tingting Xiao
Conversion of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) by electrocatalysis is significant but challenging.
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NAD(H) self-recycling whole-cell biocatalysis for the production of furoic acid and 2,5-furandicarboxylic acid from furfural via CO2 fixation
DOI: 10.1039/D5GC03156G, CommunicationMingzhe Ma, Yajie Wang
A whole-cell catalytic system facilitates the conversion of furfural to 2,5-furandicarboxylic acid through an NAD(H)-self-sufficient enzyme cascade coupled with CO2 fixation.
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D-band center modulation of Prussian blue analogues through a high-entropy strategy for aqueous potassium-ion batteries
DOI: 10.1039/D5GC03109E, PaperFuping Min, Qi Zhang, Usman Ali, Maoyu Sun, Fayin Liu, Yueqi Xu, Lu Li, Chungang Wang, Bingqiu Liu
On the basis of the d-band center theory, we employed a high-entropy strategy to regulate the d-band center of Fe-based PBAs to enhance the strength of the Fe–CN bond, which exhibits outstanding cycling stability over 10 000 cycles.
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