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Upgrading biomass-derived platform chemicals into biofuel additives in synergism with H2O2 via a ZnIn2S4 photocatalyst: towards solar fuels

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02763B, PaperArpna Jaryal, Shivali Dhingra, Nisha Mehla, Md. Ehesan Ali, Kamalakannan Kailasam
Nothing to sacrifice: a versatile photo-redox system, i.e., ZnIn2S4, for synergistically producing bio-fuel additives from biomass-derived chemicals and H2O2 (a carbon-free fuel).
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Crab shell-derived chitin nanofiber separator for high-rate potassium-ion batteries

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02731D, PaperTaohong Wang, Haoxian Shi, Junyi Wen, Donghao Yang, Boyang Zhou, Hao Xi, Zhen Zhang
Partially deacetylated chitin nanofiber separator for high-rate potassium-ion batteries
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Novel control of fractionation–depolymerization for rapid dissociation of lignin-associated xylan: toward complete lignocellulosic biomass valorization in lignin-first biorefinery

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02925B, PaperJianyu Guan, Ho-Yin Tse, Huaimin Wang, Wancheng Zhao, Raffel Dharma Patria, Molly Meng-Jung Li, Song Cheng, Tuo Wang, Shao-Yuan Leu
Harvesting sustainable aromatic chemicals from lignocellulosic biomass is a critical part of a bio-based economy.
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Phase-change azobenzene derivatives for upgraded photon energy storage and release via molecular design

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, 27,13004-13013
DOI: 10.1039/D5GC03447G, PaperXingtang Xu, Penghao Li, Chonghua Li, Bo Wu, Jie Feng, Wen-Ying Li
An innovative molecular design strategy is presented that can significantly enhance the energy densities of molecular solar thermal fuels by simultaneously storing photon energy and phase change energy.
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Membrane-free one-pot cascaded electrocatalytic redox of furfural into gamma-butyrolactone

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03829D, PaperShengqin Liu, Yangxin Jin, Qi Zhu, Xiaodan Xu, Shan Shao, Kartick Chandra Majhi, Qingguo Le, Jieming Huang, Jian Zhang, Zupeng Chen, Jason Chun-Ho Lam
A green and sustainable one-pot paired electrolysis method is introduced for the conversion of furfural (FAL), a biomass-derived platform compound, into gamma-butyrolactone (GBL).
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Green and efficient cell wall nano-reconstruction under ambient temperature towards strong cellulosic aerogels

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03785A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Xiaoying Xu, Arezu Sehati, Lukas Marcos Celada, Peter Olsén, Lars Berglund, Yuanyuan Li
A green and efficient approach for synthesizing strong cellulosic aerogels was developed through ambient-temperature wood cell wall nano-reconstruction, with a detailed study of the generation of mesoporosity and lumina nanofibril networks.
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Directional CO spillover promotes C–N coupling for highly selective electrocatalytic urea production

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03681J, PaperSheng Chang, Jing Gao, Yimin Xuan, Kui Wang
The tandem Zn@Cu electrode enables spontaneous CO spillover from Zn to Cu, which boosts the *CO coverage on Cu and facilitates efficient C–N coupling to synthesize urea.
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Correction: Evaluating the possibilities and limitations of the pyrometallurgical recycling of waste Li-ion batteries using simulation and life cycle assessment

Chemical News - 21 ottobre, 2025 - 15:23
Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC90193F, CorrectionOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Marja Rinne, Heikki Lappalainen, Mari Lundström
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Constructing a Bi–O–Mo electronic bridge bond and active sites over Bi/Bi2MoO6/Bi24O31Br10 to boost the stepwise transfer of electrons for efficient CO2 photoreduction

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02374B, PaperHuihui Ding, Huanhuan Wu, Jun Ma, Xiang Li, Shuangshuang Huai, Shijian Zhang, Wenbin Ruan, Xiuxiu Huang, Xiufang Wang, Wenjie Xie
A Bi–O–Mo bridge bond was introduced between BMO and BOB interfaces and surface metal active sites were modified. The catalyst accelerates multi-electron photocatalytic reduction processes and reduces the reaction energy barrier for CO2 reduction.
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Sustainable high-efficiency photocatalytic lithium recovery from spent LiFePO4 batteries: green process design and performance validation

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01122A, PaperYinzhuang Fang, Yurong Han, Menglong Yan, Changwen Li, Xiaolong Yan, Jinwei Li, Haowen Wei, Xianbao Wang, Tao Mei
Recycling spent lithium iron phosphate batteries is of great significance for both economic and environmental protection.
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Efficient Oxidative Cleavage of β-O-4 linkage in Lignin Model Compounds Enabled by a Simple Anderson-Type Polyoxometalate

Chemical News - 21 ottobre, 2025 - 15:23
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03832D, PaperDianyong Yang, Shuo Xie, Danqi Wu, Ji Ding, Enting Shi, Pengfei An, Sheng Dai, Li Guo, Zhenshan Hou
In this work, a simple Anderson-type polyoxometalate (POM), (NH4)4[CuMo6O24H6] (hereafter referred to as CuMo6), was utilized. This Anderson-type POM can be synthesized easily through a straightforward procedure. After undergoing a...
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Uniformly crosslinked algal bioplastic with triggerable decomposition in salt water

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02866C, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andrew E. Ashmar, Eric J. Beckman, Susan K. Fullerton-Shirey
Developing more degradable plastics is key to reducing marine pollution and microplastic-related ecological harm.
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Electrochemically relevant physical–chemical properties of tetraalkylammonium salts solutions in the renewable solvent dihydrolevoglucosenone (Cyrene®); electrochemical behaviour of some representative organic molecules

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, 27,12659-12671
DOI: 10.1039/D5GC03356J, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.José M. Ramos-Villaseñor, Jessica Sotelo-Gil, Maricarmen P. Flores-Morales, Ruben Vasquez-Medrano, Bernardo A. Frontana-Uribe
Conductivity, viscosity, IR spectroscopy of tetraalkylammonium salts solutions in DLG, and the electrochemical behavior of representative molecules was studied.
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Revealing the roles of light and heat for enhanced interfacial charge transfer in photocatalytic conversion of methanol to formaldehyde coupled with hydrogen evolution

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03911H, PaperHoukui Xiang, Wanqi Liu, Zhaokai Zeng, Jingxian Chen, Beile Lin, Guoliang Zhang, Xuhui Wei, Songbo Zhou, Tongqiang Xiong, Pengfei Li, Libing Qian
Photothermal catalytic methanol (CH3OH) dehydrogenation is a sustainable pathway for the co-production of hydrogen (H2) and formaldehyde (HCHO) under mild reaction conditions.
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Synergistic recycling of polycarbonate: efficient BPA recovery integrated with CO2 utilization to produce valuable chemicals

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02387D, PaperYue Bai, Minghao Zhang, Siming Zhu, Zhuo Wang, Yu Liu, Jianxiu Hao, Huacong Zhou, Qingqing Mei
This work introduces a synergistic strategy that simultaneously converts PC and its hydrolysis by-product CO2 into high-value products (BPA and PDO), achieving full carbon utilization with no CO2 emissions.
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Catalytic vapour phase hydrodehalogenation of 1,8-dichlorooctane over Pd@MIL-101(Cr)-NH2: a step forward in MOF-based technologies

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC04671H, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Raúl M. Guerrero, Ignacio D. Lemir, Carlos Fernández-Ruiz, Sergio Carrasco, Patricia Horcajada, David P. Serrano, Yolanda Pérez, Patricia Pizarro
Catalytic hydrodehalogenation (HDH) represents a promising strategy to remove halogens (Cl and Br) in pyrolysis oils derived from halogenated plastic waste.
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A comprehensive review on hydrothermal humic acids: synthesis, characterization, applications, and perspectives

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03926F, Tutorial ReviewHu Xu, Yangyang Li, Yexuan He, Xin Sheng, Zhiwei Zhao, Li Li
The synthesis and application of hydrothermal humic acids represent a carbon-negative pathway, analogous to the significance of basketball as a vital form of exercise.
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Intensifying hydrogen spillover over silicotungstic acid decorated carbon black-supported Ru by green plasma preparation for boosting the electrocatalytic hydrogen evolution reaction

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC03845F, PaperYunzhe Ma, Hong Li, Fei Gao, Yue Hua, Xiuling Zhang, Jingsen Zhang, Lanbo Di
Green plasma preparation intensified hydrogen spillover over silicotungstic acid decorated carbon black-supported Ru for boosting HER performance.
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2-Methyl-2-(pyridin-2-yl)malononitrile: a site-selective cyano transfer reagent for photocatalytic cyanation reactions

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, 27,12809-12818
DOI: 10.1039/D5GC03425F, PaperXiang-Chuang Tan, Lei Yan, Hao-Ni Qin, Peng-Fei Xu
Herein, we report the development of a carbon-bound radical cyanating reagent, 2-methyl-2-(pyridin-2-yl)malononitrile (MPYMN), which enables metal-free photocatalytic cyanation with high reactivity and site selectivity.
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Short and sustainable synthesis of the anticancer agent tepotinib

Chemical News - 21 ottobre, 2025 - 15:23

Green Chem., 2025, 27,12574-12579
DOI: 10.1039/D5GC04089B, CommunicationEduam O. Boeira, Angélica V. Moro, Bruce H. Lipshutz
Synthesis of the anticancer drug tepotinib was achieved in only 5 steps (3 steps in the longest linear sequence), with an overall yield of 75%.
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