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In situ capture and value-added utilization of CO2 from flue gas using ionic liquid polymer supported Zn catalyst
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02324F, PaperHongyan Ni, Kang Zhao, Shujuan Liu, Xingchao Dai, Ce Liu, Xionghou Gao, Junyi Zhang, Honghai Liu, Kuo-Wei Huang, Xinjiang Cui, Feng Shi
In this work, a porous organic polymer supported Zn catalyst (Zn@PIP-1) complexed with ionic liquid (IL), zinc halide (ZnX2), and vinyl-functionalized triphenylphosphine (p-3vPPh3) has been synthesized by a one-pot method...
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DOI: 10.1039/D5GC02324F, PaperHongyan Ni, Kang Zhao, Shujuan Liu, Xingchao Dai, Ce Liu, Xionghou Gao, Junyi Zhang, Honghai Liu, Kuo-Wei Huang, Xinjiang Cui, Feng Shi
In this work, a porous organic polymer supported Zn catalyst (Zn@PIP-1) complexed with ionic liquid (IL), zinc halide (ZnX2), and vinyl-functionalized triphenylphosphine (p-3vPPh3) has been synthesized by a one-pot method...
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Base-Catalyzed Cascades of Monosaccharide Conversion to Formic Acid: Isotope Tracking Reveals Pathways and Their Optimal Usage under Mild Conditions in Water
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01907A, PaperStefan S. Warthegau, Mette-Maya Siewertsen, Robert Madsen, Sebastian Meier
Carbohydrates are promising substrates for future precursors and fuels if operationally simple and high-yielding processes are developed. Attractive products include formic acid as a liquid-phase hydrogen-storage material that is safe...
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DOI: 10.1039/D5GC01907A, PaperStefan S. Warthegau, Mette-Maya Siewertsen, Robert Madsen, Sebastian Meier
Carbohydrates are promising substrates for future precursors and fuels if operationally simple and high-yielding processes are developed. Attractive products include formic acid as a liquid-phase hydrogen-storage material that is safe...
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Ambient Mechanosynthesis of Flexible Two-dimensional Covalent Organic Frameworks
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01728A, PaperYogendra Nailwal, Bryson Baker, Ziad Alsudairy, Mustapha El Hariri El Nokab, Qingsong Zhang, Tuo Wang, Songliang Cai, Yi Liu, Xinle Li
Flexible two-dimensional covalent organic frameworks (2D COFs) constructed from nonplanar building blocks represent an emerging paradigm in COF design. Nevertheless, the prevailing solvothermal synthesis suffers from low time efficiency, environmental...
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DOI: 10.1039/D5GC01728A, PaperYogendra Nailwal, Bryson Baker, Ziad Alsudairy, Mustapha El Hariri El Nokab, Qingsong Zhang, Tuo Wang, Songliang Cai, Yi Liu, Xinle Li
Flexible two-dimensional covalent organic frameworks (2D COFs) constructed from nonplanar building blocks represent an emerging paradigm in COF design. Nevertheless, the prevailing solvothermal synthesis suffers from low time efficiency, environmental...
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Ambient and green processing of lead-free double perovskite Cs2AgBiBr6 films
DOI: 10.1039/D5GC00722D, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Qian Chen, Abhinav K. Singh, Hissah Alghathami, Xuzhao Liu, Kun Huang, Andrew G. Thomas, Richard J. Curry, Laurie J. Phillips, Amanda J. HughesA green and simple method for processing high-quality lead-free perovskite Cs2AgBiBr6 films under ambient conditions for future optoelectronic applications.
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Efficient low-temperature depolymerization of polycarbonate catalyzed by lanthanum β-diketonate complexes
DOI: 10.1039/D5GC00829H, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Yuho Kinbara, Haruro Ishitani, Shū KobayashiOptimal lanthanum diketonate complex enabled polycarbonate depolymerization below 60 °C, yielding monomers in high yields. Slurrying the polycarbonate sample with toluene prior to depolymerization accelerated the methanolysis reaction.
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A self-adhesive glutenin-based coating cross-linked by genipin for suppressing microplastic shedding in harsh environments
DOI: 10.1039/D4GC06154C, PaperYulun Chen, Qingrun Liu, Jianjun Ding, Shaofeng Yuan, Hang Yu, Yahui Guo, Yuliang Cheng, He Qian, Weirong Yao
The large-scale application of plastic packaging has raised concerns on the generation of microplastics (MPs).
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Electrochemical Ni–H Catalysis for Selective Tail-to-Tail Reductive Dimerization of Terminal Alkynes to 2,3-Dibranched Butadienes
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02238J, PaperShide Lv, Mingming Yu, Yinglong Ni, Tiantian Huang, Hong Yi, Aiwen Lei
Reductive dimerization of terminal alkynes offers a direct route to diverse 1,3-diene frameworks, including linear, 1,3-, and 2,3-branched structures. Achieving precise regioselectivity, particularly for 2,3-dibranched butadienes, remains a significant challenge....
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DOI: 10.1039/D5GC02238J, PaperShide Lv, Mingming Yu, Yinglong Ni, Tiantian Huang, Hong Yi, Aiwen Lei
Reductive dimerization of terminal alkynes offers a direct route to diverse 1,3-diene frameworks, including linear, 1,3-, and 2,3-branched structures. Achieving precise regioselectivity, particularly for 2,3-dibranched butadienes, remains a significant challenge....
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Photocatalytic 1,2-thiosulfonylation of alkenes with thiophenols and sulfonyl chlorides promoted by directly knitted copper polymers
DOI: 10.1039/D5GC02121A, PaperLijie Chen, Kai Zhang, Yajing Shen, Zhen Chen, Weiwei Fang
A three-component photocatalytic 1,2-thiosulfonylation reaction of alkenes with thiophenols and sulfonyl chloride was promoted by using a rationally designed copper-containing hypercrosslinked polymer via the “direct knitting” strategy.
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Visible-light-mediated late-stage N-functionalization of unprotected peptides: introducing the aza-Zimmerman–O'Connell–Griffin reaction
DOI: 10.1039/D5GC02108A, Communication
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Sara Bacaicoa, Mario Martos, Wilma Yhlen Graf, August Runemark, Ganesh H. Shinde, Ganesh S. Ghotekar, Henrik SundénA sustainable, reagent-free method for amide synthesis and peptide functionalization via photoinduced ZOG rearrangement. High-yielding, purification without chromatography, and driven solely by light—ideal for greener peptide modification.
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Overcoming the conversion reaction limitation with a dual-phase sulfide-based cathode for all-solid-state lithium–sulfur batteries
DOI: 10.1039/D5GC01720C, PaperRuojian Ma, Yingzuo He, Minghao Ruan, Ruyi Fang, Xinxu Wang, Jun Zhang, Yongping Gan, Xinping He, Hui Huang, Xinhui Xia, Wenkui Zhang, Xinyong Tao, Min Fan, Yang Xia
A dual-phase sulfide-based cathode integrating CoS2 as an active site enhances cathode utilization and cycling stability of all-solid-state lithium–sulfur batteries.
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Amine-functionalized lignin hydrogels for high-performance N-type ionic thermoelectric materials
DOI: 10.1039/D4GC06542E, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nazish Jabeen, Clara M. Gómez, Rafael Muñoz-Espí, Andrés Cantarero, Maurice N. Collins, Mario CulebrasAmine-functionalized lignin hydrogels serve as stable n-type thermoelectric materials through the thermodiffusion effect, offering efficient energy harvesting platforms.
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Intensification of wheat straw autohydrolysis at minimal water input: Advancing a novel hemicellulose-first approach
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02300A, PaperStanislav Parsin, Martin Kaltschmitt
The autohydrolysis of wheat straw, as a key step in a hemicellulose-first concept, was investigated with a focus on separating xylose-based oligomers and water-soluble polymers. The feedstock preparation and the...
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DOI: 10.1039/D5GC02300A, PaperStanislav Parsin, Martin Kaltschmitt
The autohydrolysis of wheat straw, as a key step in a hemicellulose-first concept, was investigated with a focus on separating xylose-based oligomers and water-soluble polymers. The feedstock preparation and the...
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The reaction of maleic anhydride with alkenes: a review on the mechanisms involved in the reaction of maleic anhydride with lipids
DOI: 10.1039/D5GC00543D, Critical ReviewShamseldin A. Mohamed, Mildrède Debello, Justine Cantot, Stéphane Lavaud, Guillaume Chollet, Clémence Queffélec, Emmanuel Chailleux
Maleic anhydride is one of the most widely used anhydrides after acetic and phthalic anhydride and its market has grown rapidly over the last century.
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Green solvent-based separation and regeneration of layered ternary cathode materials for sustainable lithium-ion battery recycling
DOI: 10.1039/D5GC01636C, PaperLiying Ou, Ying Zhang, Pengwei Li, Kai Zhu, Yinyi Gao, Dianxue Cao
Based on TEP solvent for separating electrode materials, efficient dissociation of NCM from binders and conductive agents is achieved, providing a green separation pathway for the targeted recycling of precious metals and Li resources in spent LIBs.
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Mechanism of ultrasound-enhanced alkaline selective leaching of zinc from steel waste: experimental and DFT simulation analysis
DOI: 10.1039/D5GC02296G, PaperChunfu Xin, Shenxu Bao, Yimin Zhang, Bo Chen, Wei Ding, Hongwei Zhang, Shuo Liu
Ultrasound-enhanced alkaline leaching selectively extracts zinc from steel waste via cavitation-driven mineral destruction and preferential ZnO dissolution, enabling efficient hazardous waste upcycling with less reagents and time.
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Recycling of polystyrene waste to mono-aromatic hydrocarbons via intermittent thermal scission
DOI: 10.1039/D5GC01563D, PaperZhuohan Lin, Jiaxin Li, Wang Xu, Qiaohui Ruan, Jiakang Hu, Peiqing Yuan, Yan Li
Tunable depolymerization–repolymerization during polystyrene pyrolysis enables selective production of mono-aromatic hydrocarbons (MAHs), achieving >90% liquid yield with ~95% MAHs. The strategy applies to various polystyrene feedstocks.
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Amino and hydroxyl functionalization of nucleosides via resonant acoustic mixing
DOI: 10.1039/D5GC01768H, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Julian Marlyn, Olivia Del Carlo, James D. Thorpe, Masad J. DamhaThis study finds resonant acoustic mixing to be an effective tool in solvent minimization and rate acceleration in a variety of functionalization and protection reactions on nucleosides.
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Photo-Induced FeCl3-catalysed direct desulfurizative chlorination of thio-containing aromatics at room temperature
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01859E, CommunicationMingjing Deng, Zhaolun Ma, Ke Liu, Bingji Li, Jing Wu, Longyang Dian
We report herein a FeCl₃-catalyzed desulfurizative chlorination of thiol-containing aromatics at room temperature under near visible light irradiation. This study demonstrates that FeCl₃ can effectively catalyze the direct chlorination of...
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DOI: 10.1039/D5GC01859E, CommunicationMingjing Deng, Zhaolun Ma, Ke Liu, Bingji Li, Jing Wu, Longyang Dian
We report herein a FeCl₃-catalyzed desulfurizative chlorination of thiol-containing aromatics at room temperature under near visible light irradiation. This study demonstrates that FeCl₃ can effectively catalyze the direct chlorination of...
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A green strategy for selective recovery of valuable metals from spent lithium-ion batteries through a waste graphite-assisted sulfation process
DOI: 10.1039/D5GC01464F, PaperMinyu He, Fagen Zhou, Sohrab Rohani, Charles Q. Jia, Dong Wang, Wenhao Yu, Liumei Teng, Fei Meng, Qingcai Liu, Weizao Liu
This research introduces a green recycling and regeneration method for spent lithium-ion batteries, demonstrating significant environmental benefits.
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Streamer-spark discharge at the water surface as a source of plasma-activated water: nitrogen fixation yields and biocidal efficiency
DOI: 10.1039/D5GC01343G, PaperJiří Fujera, Petr Hoffer, Václav Prukner, Palma Rosa Rotondo, Garima Arora, Vít Jirásek, Rita Milvia De Miccolis Angelini, Petr Lukeš, Milan Šimek
The plasma filaments propagating along the air–water interface offer a useful approach to enhance the transport of reactive species from plasma into the liquid medium.
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