Chemical News

Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02911B, PaperRenhua Su, Jiantao Zhang, Yanfu Jiang, Xian Jiang, Peng Zhou, Jingxing Jiang, Weibing Liu
We reported a visible-light-driven, photocatalyst-free bisperoxidation of aryl alkenes with tert-butyl hydroperoxide (TBHP), enabling the regioselective synthesis of α,β-bisperoxides. To our knowledge, this represents the first radical reaction utilizing TBHP...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01806D, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Giorgia Crigna, Davide Moscatelli, Tuomo Sainio
A series of hydroxycarboxylic acids (HAs) with excellent hydrophilic properties are produced from alkali treatment of cellulose–containing materials. The great majority of these hydroxy acids is constituted by glucoisosaccharinic acids...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02482J, CommunicationHan Wang, Jing Feng, Dan-Ni Liu, Mingming Yu, Ze-Feng Xu, Chuan-Ying Li
The synthesis of aminated N-heterocycles is a critical area in organic synthetic chemistry. But some issues need to be addressed for traditional amination of N-heterocycles, such as the need of...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01983D, PaperJiahui Liu, Chuying Li, Yanwei He, Bo Deng, Haitao Huang, Siwei Liu, Yi Zhang
The widespread use of polyimide varnish in semiconductors, packaging, and flexible displays has created increasing demand for efficient and environmentally friendly preparation. Compared to polyamic acid varnish, polyimide varnish offers...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01820J, PaperMiao Ma, Lixiao Shen, Pan Guo, Bo Liu, Ziyu Zhang, Yunfei Xia, Zigang Zhao, Aibing Chen, Yunlong Zhang, Lei Zhao, Zhenbo Wang
The strong adsorption of ionomer sulfonate groups (-SO3-) onto platinum (Pt) nanoparticles significantly hinders the catalytic activity and mass transport at the Pt/ionomer interface, compromising electrode reaction efficiency in proton...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02994E, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stefan Eichwald, Hesam Ostovari, Hannah Minten, Janine Meyer-Waßewitz, Dieter Förtsch, Niklas von der Assen
Evaluating the environmental impacts of chemicals is crucial for a sustainable chemical industry. While Life Cycle Assessment (LCA) is recommended for evaluating environmental impacts, collecting chemical life-cycle data is often...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01810B, PaperLucie M. Lindenbeck, Silas Brand, Finn Schatz, Franka Stallmann, Nele Petersen, Björn B. Beele, Jessica Pichler, Marcella Frauscher, Raphaela Süss, Pascal Olschowski, Serhiy Budnyk, Adam Slabon, Bruno V.M. Rodrigues
This investigation presents a one-pot electrochemical depolymerization of lignin, coupled with in-situ extraction, to enhance product recovery and process efficiency. Kraft lignin was dissolved in an aqueous sodium carbonate solution...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01029B, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Leonid Shupletsov, Alina Christin Schieck, Irena Senkovska, Volodymyr Bon, Stefan Kaskel
Herein we report a novel and green synthetic approach for pyrazolate-based metal-organic frameworks (MOFs) as demonstrated by the three prominent examples of this material class: [Ni(bdp)]n, and two supramolecular isomers...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01651G, CommunicationWeilong Lin, Jiayu Liang, Shuping Wang, Xingda Zhao
The trifluoromethyl (CF3) group has emerged as a privileged structural motif in pharmaceutical compounds and biologically active molecules, leading to a significant demand for efficient synthetic methodologies to incorporate the...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC03111G, Critical ReviewLisha Sheng, Hailong Ning, Yi Wang, Chengyi Li, Shengtao Huang, Yuquan Zhang, Bo Xu, Zhenqian Chen
Porous liquids are a novel class of porous materials, which integrate the permanent porosity of solids with the fluidity of liquids. By rational combination of the porous solids and liquid...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01804H, Tutorial ReviewBao-Jie Wang, Yi-Le Song, Ke Li, Li-Rong Wen, Ming Li, Jiaxiu Liu, Weisi Guo, Lin-Bao Zhang
Organic electrochemical synthesis has become a practical and environmentally friendly synthesis method, widely used in oxidation, reduction, and redox-neutral reactions. By precisely controlling the current or potential, it is possible...
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC02521D, CommunicationQingge Zhao, Mengyu Peng, Huimin Li, Longqiang Zhao, Xinyue Song, Peiyao Zhao, Shoucai Wang, Guangbin Jiang, Fanghua Ji
We present an innovative photocatalytic system for sustainable quinolin-2(1H)-one synthesis with broad substrate scope under mild, oxidant-free conditions, overcoming limitations of harsh traditional methods and high-pressure CO dependency. A complementary...
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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02301G, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alexander R. Craze, Ryan. W. F. Kerr, Thomas M. McGuire, Lukas Wille, Charlotte. K. Williams
Properties of bio-derived poly(L-lactide) are improved by block polymer additives which deliver efficient chemical recycling and enzymatic hydrolysis. Blends compete with poly(acrylonitrile-butadiene-styrene) and high impact polystyrene.
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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01051A, PaperTian Zhao, Pengcheng Xiao, Saiqun Nie, Jiangrong Yu, Shilin Peng, Jiayao Chen, Fuli Luo, Yi Chen
Pure BC separator lack channels, causing loose Zn2+ deposition and dendrites. In situ UiO-66 growth on BC forms hierarchical pores for uniform Zn2+ diffusion/deposition, suppressing dendrites, improving cycling and reducing energy use and emissions.
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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01711D, PaperA. Yaxuan Zheng, B. Siyu Han, C. Yuxin Sun, D. Zhangpei Chen, E. Yuqiu Huo, F. Jianshe Hu
The rational design of efficient photocatalysts is critical for solar-driven chemical conversions.
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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC02248G, PaperZhimin Du, Peixiang Gao, Yuxiang Chen, Yingming Zhang, Yongzhi Liu, Xuejing Qiu, Lingling Xie
Co-recycling of spent cathode/anode via redox-mediated lithiation enables anodic de-lithiation and cathodic re-lithiation, regenerating Al, Cu, graphite and LiFePO4.
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Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01618E, PaperXinjun He, Mengqiao Gao, Fukun Li, Zhiyang Tang, Jie Qu, Jinxing Long, Qiang Zeng, Xuehui Li
Catalytic hydrogenolysis of lignin has attracted steady attentions in regard of producing high-value aromatic chemicals from the renewable resource and achieving the “carbon neutrality” goal. However, current techniques for lignin...
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Green Chem., 2025, 27,8360-8385
DOI: 10.1039/D4GC06386D, Critical Review Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Emma Chevé-Kools, Young Hae Choi, Catherine Roullier, Gwenaël Ruprich-Robert, Raphaël Grougnet, Florence Chapeland-Leclerc, Frank Hollmann
This review first provides a comprehensive overview of NaDES theory and subsequently explores all potential applications of NaDES in the pharmaceutical industry, highlighting overlooked issues such as toxicity and process limitations.
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Green Chem., 2025, 27,8505-8516
DOI: 10.1039/D5GC00114E, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Stefano Poli, Claude Poleunis, Matteo Miola, Dominic Gerlach, Petra Rudolf, Arnaud Delcorte, Hans Lammers, Matheus T. de Groot, Dulce M. Morales, Paolo P. Pescarmona
A regeneration strategy combined with the tuning of traces of iron in the electrolyte enabled achieving high activity and enhanced stability of nickel electrodes in the oxygen evolution reaction (OER).
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Green Chem., 2025, Advance Article
DOI: 10.1039/D5GC01906K, Critical ReviewMuhammad Tahir Khalil, Xianli Wu, Shuling Liu, Yanyan Liu, Saima Ashraf, Ruofan Shen, Huanhuan Zhang, Zhikun Peng, Jianchun Jiang, Baojun Li
The catalytic CO2 to methanol conversion enables sustainable fuel production and emissions reduction. Advanced catalysts, reaction mechanisms, and process optimization are critically analyzed.
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