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Aggiornato: 2 giorni 8 ore fa
Interface engineering via in situ constructed zincophilic gradient interphases for high-performance zinc-ion batteries in wide temperature ranges
DOI: 10.1039/D5GC03908H, PaperYi-Yang Bi, Song-Lin Tian, Yang Yu, Yu Zhang, Lian-Shan Sun, Jian Li, Wan-Qiang Liu, Kai Li, Gang Huang
With the steadily rising demand for energy storage devices, there is an increasing need for high-performance batteries.
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An unconventional photochemical amide synthesis from excited-state nitroarenes
DOI: 10.1039/D5GC03649F, PaperZengping Wang, Xiaofang Zhai, Pengtao Bai, Li Fang, Shaojun Zheng, Jiajia Zhao, Fu Yang, Chen Xu, Heng Song
Based on the bifunctional nature of photoexcited nitroarenes, a novel photochemical approach for amide synthesis was developed.
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Mechanochemical ball milling as an emerging tool in chemical recycling and upcycling of waste polymers
DOI: 10.1039/D5GC03507D, Critical Review
Open Access 
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Anamarija Briš, Davor Margetić, Vjekoslav ŠtrukilA comprehensive review of mechanochemical recycling and upcycling of waste polymers by ball milling is critically assessed, highlighting its efficiency and potential for the depolymerization or degradation of waste plastics.
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Interfacial engineering-triggered electronic regulation of Re and CoP hollow multi-shelled structure toward high-activity electrochemical water splitting
DOI: 10.1039/D5GC03290C, PaperGuangyao Zhou, Mingxin Pang, Jing Li, Bin He, Zhijuan Li, Yawen Tang
Cooperation between interfacial engineering and a hollow multi-shelled structure boosts the water electrolysis performance of Re/CoP.
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Porous core–shell CuAu@Cu2O catalyst for acidic C–N coupling toward urea electrosynthesis from CO2 and nitrate
DOI: 10.1039/D5GC04150C, PaperXiang Ji, Yaodong Yu, Yujia Guan, Jianping Lai, Lei Wang
The porous core-shell CuAu@Cu2O catalyst promotes C–N bond formation and suppresses the hydrogen evolution side reaction under acidic conditions, enabling efficient electrocatalytic urea synthesis from CO2 and nitrate.
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Comparative reactor, process, techno-economic, and life cycle emissions assessment of ethylene production via electrified and thermal steam cracking
DOI: 10.1039/D5GC02960K, PaperAlexandre Cattry, Chaitanya Vuppanapalli, Dharik S. Mallapragada
Model-based evaluation of reactor and process-level performance for electrified ethane steam cracking compared to conventional thermal cracking with and without CO2 capture.
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Green synthesis strategy for Ti3C2 MXenes based on SnCl2-assisted etching with a small amount of HF
DOI: 10.1039/D5GC03932K, PaperPei Zhang, Haixiang Wang, Yiting Guo, Xiaohua Zhang, Jianfeng Zhu
Replacing concentrated HF with low-toxicity SnCl2 as the primary etchant reduces toxicity and operational risk. The resulting Ti3C2 electrode delivers a specific capacitance of 186.7 F g−1, surpassing that of conventional HF-etched analogues.
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Electrochemical reduction of ammonia-captured CO2 to CO over a nickel single-atom catalyst
DOI: 10.1039/D5GC02515J, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sujin Kang, Lun An, Tianlei Li, Long Qi, Wenyu Huang, Wenzhen LiSustainable CO production from ammonia-captured CO2 is achieved using a nickel single-atom catalyst, avoiding purification and enhancing efficiency through electrode structure optimization.
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Photocatalytic transformation of aliphatic heterocycles and electron-poor alkenes into functionalized heteroarenes
DOI: 10.1039/D5GC04418A, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lorenzo Di Terlizzi, Davide Ravelli, Burkhard KönigThe merger of decatungstate photocatalysis and cobaloxime catalysis enabled the preparation of functionalized heteroarenes via a hydroalkylation/aromatization sequence starting from largely available aliphatic heterocycles and electron-poor olefins.
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The position-tuned nitrogen atom in Ni(II)-metalated covalent organic frameworks enables highly efficient and sustainable C–N coupling
DOI: 10.1039/D5GC03438H, PaperRui Zhang, Jinyang Hai, Huiying Chen, Mingxiang Zhu, Fang Zhang
Ni@Bpma-COF with highly efficient electron transfer (via regulating the electron transport distance and electron acceptance ability of the metal center) enables efficient and green Buchwald-Hartwig amination reactions.
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Correction: Hydrothermal liquefaction vs. fast/flash pyrolysis for biomass-to-biofuel conversion: new insights and comparative review of liquid biofuel yield, composition, and properties
Green Chem., 2025, 27,12483-12486
DOI: 10.1039/D5GC90176F, Correction Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Farid Alizad Oghyanous, Cigdem Eskicioglu
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DOI: 10.1039/D5GC90176F, Correction
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Farid Alizad Oghyanous, Cigdem EskiciogluThe content of this RSS Feed (c) The Royal Society of Chemistry
In situ cyanide functionalization of ZIF-8 by γ-irradiation for photochemical removal of uranium
DOI: 10.1039/D5GC04222D, PaperYukun Zhang, Chong Chen, Changjiang Hu, Jianfeng Zhao, Jun Ma
A sustainable γ-ray strategy for in situ –CN generation in ZIF-8 avoids toxic cyanide. The resulting functionalized ZIF-8, coordinated with UO22+ ions through the –CN groups, demonstrates exceptional photocatalytic U(VI) reduction performance.
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Sustainable silica microcapsules
DOI: 10.1039/D5GC03298A, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.O. Norvilaite, C. Lindsay, M. J. Rymaruk, P. Taylor, S. P. ArmesSustainable micron-sized silica microcapsules for potential agrochemical applications are prepared under mild conditions at relatively high solids using a wholly aqueous formulation involving cheap, commercially available reagents.
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Plastic photoreforming: catalytic production of hydrogen and valuable chemicals
DOI: 10.1039/D5GC02621K, Tutorial ReviewHeng Li, Yeqiong Huang, Yueyang Zhang, Haiyan Li, Chengcheng Shen, Dong Xia, Yanmei Zheng
This review summarizes advances in plastic photoreforming for hydrogen production, aiming to promote the development of sustainable and efficient technologies for plastic waste degradation and green energy recovery.
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Unlocking the potential of plastic recycling processes with the integration of membrane technology: a focus on PET valorisation
DOI: 10.1039/D5GC03012A, Perspective
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hamidreza Mahdavi, Laila Halim, Selina Giles, Xiaoheng Jin, Leonie van 't Hag, Zongli Xie, Matthew R. Hill, Benny D. FreemanPlastics have transformed society but generate waste; integrating membrane technologies into recycling supports pretreatment, impurity separation, valuable-component purification, and waste treatment for higher-quality, lower-energy circularity.
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Evaluation of Ni/TiO2 catalysts in the semi-hydrogenation of alkynols under mild conditions in water
DOI: 10.1039/D5GC03626G, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ajay Tomer, Laurent Djakovitch, Noémie PerretSelective hydrogenation of 2-methyl-3-butyn-2-ol to 2-methyl-3-butene-2-ol in water at room temperature with titania-supported Ni catalysts.
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Modular engineering a Shewanella oneidensis–CdS@rGO artificial photosynthetic biohybrid to accelerate photoelectron transfer and conversion for enhanced hydrogen production
DOI: 10.1039/D5GC01001B, PaperWenliang Xu, Qijing Liu, Qinran Ding, Yan Zhang, Junqi Zhang, Chao Li, Huan Yu, Baocai Zhang, Jie Yang, Cheng Zhong, Wenyu Lu, Guosheng Xin, Hao Song, Feng Li
A modular engineering strategy, including increasing transmembrane photoelectron uptake, improving intracellular photoelectron conversion, and accelerating interfacial photoelectron transfer.
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Visible light-driven modular synthesis of aza-β-lactams via a dual photochemical cascade
DOI: 10.1039/D5GC03481G, PaperImtiaz Ahmed, Nikita Gupta, Plaban Jyoti Sarma, Shilpa Neog, Vijay Kumar Das
Visible light unlocks a mild, transition metal-free pathway toward [2+2] cycloaddition of in situ generated ketenes with azoarenes, forging aza-β-lactams with up to 99% yield and broad scope—a green pathway to valuable scaffolds.
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Recent advances in vanadium-based NASICON-structured cathode materials for sodium-ion batteries
DOI: 10.1039/D5GC03154K, Tutorial ReviewQianchen Wang, LiYao Lu, Zhonghao Lv, Yuhang Xin, Zimo Zhang, Yingshuai Wang, Hongcai Gao
Vanadium-based NASICON cathodes stand out in sodium-ion batteries via three-electron transfer.
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Defect-engineered MOF-801 as a redox-active intercalation battery-type capacitive deionization cathode: mechanistic insights into selective calcium ion removal
DOI: 10.1039/D5GC02438B, PaperShu Zhou, Dong Wang, Huangzhao Wei, Hongchao Ma, Guowen Wang
The channels of SS-MOF-801 facilitate capturing the thick hydration shell of Ca2+·nH2O, reducing the hydration energy barrier. The defect oxygen groups and SDBS work together to selectively adsorb Ca2+ from multi-ion solutions via redox processes.
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