Chemical News
The role of N-containing carbohydrates in organic catalysis: a review
DOI: 10.1039/D5GC03614C, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kui ZengThis review highlights recent advances in using nitrogen-containing carbohydrates (NCCs) as renewable feedstocks, chiral ligands, and organocatalysts, showcasing their potential to drive sustainable, stereocontrolled organic synthesis.
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Hierarchical Co3O4 microspheres via dual-metal doping-induced nanorod self-assembly: toward high-efficiency bifunctional cathode catalysts for Li–O2 batteries
DOI: 10.1039/D5GC03466C, PaperYongji Xia, Sheng Lin, Jian Yan, Renjie Xu, Yingpeng Du, Chunxiao Song, Dong-Liang Peng, Zhidong Zhou, Jiajia Han, Guanghui Yue
The introduction of Cu and Mn can regulate the directional growth of Co3O4 nanorods, reduce the aggregation of small particles, and change the ratio of Co3+/Co2+, thereby achieving excellent catalytic performance.
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Life cycle analysis of sustainable H2 production and hydrogenation of chemicals in a large-scale coupled photoelectrochemical system
DOI: 10.1039/D5GC02117K, PaperXinyi Zhang, Michael Schwarze, Ferry Anggoro Ardy Nugroho, Muhammad Roil Bilad, Carol Sze Ki Lin, Reinhard Schomäcker, Roel van de Krol, Fatwa F. Abdi
This article presents a comprehensive life cycle analysis of a photoelectrochemical water splitting system coupled with hydrogenation of feedstock into valorization chemicals.
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Enhanced methane combustion over monoclinic single-site Mn-containing nanosized MFI zeolite catalyst
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC04039F, PaperMarco Giuseppe Geloso, Sajjad Ghojavand, Chunzheng Wang, Edwin Clatworthy, Oleg I. Lebedev, Diogenes Honorato-Piva, Francesco Dalena, Glorija Medak, Aymeric Magisson, Hristiyan A Aleksandrov, Georgi N. Vayssilov, Svetlana Mintova
Our study addresses a critical challenge in the development of thermally stable, selective, and efficient catalysts for lean methane (CH4) combustion. This reaction is of paramount importance for environmental remediation,...
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DOI: 10.1039/D5GC04039F, PaperMarco Giuseppe Geloso, Sajjad Ghojavand, Chunzheng Wang, Edwin Clatworthy, Oleg I. Lebedev, Diogenes Honorato-Piva, Francesco Dalena, Glorija Medak, Aymeric Magisson, Hristiyan A Aleksandrov, Georgi N. Vayssilov, Svetlana Mintova
Our study addresses a critical challenge in the development of thermally stable, selective, and efficient catalysts for lean methane (CH4) combustion. This reaction is of paramount importance for environmental remediation,...
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Research progress in C2+ products in electrocatalytic methane valorization
DOI: 10.1039/D5GC04491J, PerspectiveZijing Suo, Yuyao Sun, Jianping Lai, Lei Wang
Strategies and pathways for electrocatalytic methane conversion to C2+ products.
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Oxygen evolution reaction electrocatalysts for green hydrogen production in seawater: enhancement mechanism in catalytic activity and durability
DOI: 10.1039/D5GC03577E, PerspectiveBingxu Wang, Xiao Tang, Fahao Sun, Sailong Wang, Xiaobin Liu, Jianping Lai, Jingqi Chi, Lei Wang
This study focuses on MSOEs as electrocatalysts for seawater oxygen evolution reaction (OER), summarizes strategies for improving the OER activity and durability, and discusses OER in seawater its improvement strategies based on sustainability.
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Design and synthesis of biobased superhydrophobic biochar catalyst derived from Citrus sinensis for biodiesel production using inedible oil feedstocks
DOI: 10.1039/D5GC03788C, PaperSupongsenla Ao, Shuyang Zhang, Peter K. Karoki, Rohit Kousika, Gabriel A. Goenaga-Jimenez, Tyler McCoy, Wei Wang, Nara Han, Chang Geun Yoo, Chandrakanta Guchhait, Bimalendu Adhikari, Xianzhi Meng, Thomas A. Zawodzinski, Samuel Lalthazuala Rokhum, Arthur J. Ragauskas
A superhydrophobic biochar catalyst from orange peel sustains ∼99% biodiesel yield for 10 cycles by resisting water-driven deactivation, while LCA highlights its lower carbon footprint relative to conventional solid acid catalysts.
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Different paths lead to the same destination: a highly efficient TMSOTf/HFIP catalytic system for large-scale synthesis of fluoroalkyl-containing 4,4′-methylenedianiline (MDA) monomers
DOI: 10.1039/D5GC03637B, PaperZiyan Wu, Guodong Fang, Xindi Li, Yuhao Wu, Jinshan Li, Yan Feng, Jialin Xie, Xueqing Zhou, Zhenchang Wen, Chunman Jia
A new method is presented for the efficient synthesis of challenging 3FpDA diamine monomers from anilines and fluoral hydrate at the kilogram level.
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Technology of lignin modification: progress in specialty and green adhesives’ mechanical properties
DOI: 10.1039/D5GC03303A, Tutorial ReviewHaijing Ma, Ziyang Zhang, Yuli Wang, Jiangbo Wang, Heyu Chen, Shaohua Jiang, Xiaoshuai Han
Modification of lignin and its application in specialty and green adhesives gives excellent properties to the adhesive.
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Co–O–Si interface engineering for sustainable ammonia synthesis with nearly 100% faradaic efficiency
DOI: 10.1039/D5GC04243G, PaperWeize Chen, Hui Su, Xuan Zheng, Xiaoping Chen, Jing Tang, Yi Li, Qingxiang Wang, Yun Ling
Co–O–Si interfacial engineering in hierarchical CoSiOx nanoflowers with abundant oxygen vacancies enables nearly 100% faradaic efficiency for selective eight-electron nitrate-to-ammonia conversion under ambient conditions.
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Synergistic microwave–metal interactions in polyurethane/biomass co-pyrolysis: unraveling reaction mechanisms and product selectivity control
DOI: 10.1039/D5GC03270A, PaperYu Ni, Shanjian Liu, Weiming Yi, Jiyan Ma, Qing Dong, Chengxizi Zhang
Metal-modified biochar catalysts induce microwave–metal synergistic effects during polyurethane–biomass co-pyrolysis. These effects enhance thermal and electromagnetic interactions, promoting the selective formation of nitrogen-containing chemicals.
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ATP-independent enzymatic cascade for chitin-to-glucose bioconversion
DOI: 10.1039/D5GC04343C, PaperJin-Da Zhuang, Jin-Min Shi, Ai-Min Lu, Li Liu, Josef Voglmeir
Chitin, a widely available biomass, was efficiently converted to glucose using a modular multienzyme cascade without requiring ATP.
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External photocatalyst- and additive-free visible light-driven direct benzylic C–H functionalization with 1,2-diketones
DOI: 10.1039/D5GC04600A, PaperXiaofeng Yu, Nan Huang, Yuhua Lu, Yanping Huo, Yang Gao, Xianwei Li, Qian Chen
A visible light-driven direct benzylic C–H functionalization with 1,2-diketones has been achieved via cross-coupling between benzylic radicals and ketyl radicals.
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A greener strategy for ultra-fast adsorption-promoted ozonation of livestock-excreted pharmaceuticals by co-pyrolysis of steel converter slag and biogas residues: synergistic effects, environmental impacts and DFT study
DOI: 10.1039/D5GC04029A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Muhammad Noman, Dinkayehu Tsegaye Awugichew, Guangwei Yu, Tekuma Abdisa BakareChina is the biggest pork-producing country, consequently raising serious environmental threats, due to the direct irrigation of untreated swine urine containing emerging toxic antibiotic residues like ofloxacin.
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Oxidation-CO2 leaching of spent LiFePO4 for lithium extraction and impurity control
DOI: 10.1039/D5GC03328D, PaperZhiming Yan, You Wu, Zepeng Lv, Shiying Qin, Mingrui Yang, Anwar Sattar, Zushu Li
The proposed process for recycling end-of-life LFP.
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Delamination and deinking of colored multilayer flexible plastic packaging via selective aminolysis of polyurethane and acrylate based adhesives
DOI: 10.1039/D5GC02667A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sibel Ügdüler, Tobias De Somer, Noa Collier, Martijn Roosen, Steven De MeesterThis study demonstrates selective adhesive aminolysis enabling delamination and deinking of multilayer packaging without compromising the integrity of the primary polymer substrates.
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A bifunctional recyclable Gemini surfactant catalyst for oxidative nitroso Diels–Alder reactions in water
DOI: 10.1039/D5GC03912F, PaperLongxia Jia, Hongling Liu, Weiwei Shi, Yingru Xu, Ruihan Sun, Jia Zuo, Bin Wang, Jianjian Huang, Fangrui Zhong, Dangui Wang
A novel bifunctional cationic Gemini iodide catalyst was developed, enabling micelle-catalyzed oxidative nitroso Diels–Alder reactions in aqueous media.
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Mechanochemical-assisted carbothermal reduction for recycling spent lithium-ion batteries: a green and economical recycling strategy
DOI: 10.1039/D5GC03877D, PaperWeixin Li, Pengwei Li, Bai Song, Peng Yue, Yinyi Gao, Dianxue Cao, Kai Zhu
Ball milling spent cathode materials with graphite and H2O2 can reduce the temperature of the carbothermal reduction reaction and decrease graphite consumption, making it highly environmentally friendly.
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Sulphur-doped graphene quantum dot electrolyte additives for enhanced cycling stability of aqueous zinc-ion batteries
DOI: 10.1039/D5GC02211H, PaperJuanyun Li, Bin Wang, Zaohong Zhang, Peng Xie, Yanming Huang, Chengjie Xin, Ding Chen
Sulfur-doped graphene quantum dots with abundant functional groups were synthesized and their incorporation as electrolyte additives disrupts conventional solvated structures, enabling excellent electrochemical performance in assembled batteries.
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Upcycling spent polycrystal LiNi1/3Co1/3Mn1/3O2 cathodes into single-crystal Ni-rich materials via the “four-in-one” upcycling regeneration strategy
DOI: 10.1039/D5GC03333K, PaperFu Wan, Da Yang, Ruiqi Liu, Yupeng Lin, Wenwei Yin, Kaida Hu, Changding Wang, Yujie Zheng, Weigen Chen
The “four-in-one” upgraded regeneration strategy achieved the directional regeneration of waste low-nickel polycrystalline NCM111 to the molybdenum-gradient-doped nickel-rich single crystal NCM811.
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