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Hydrogen spillover boosts PET upcycling to aviation fuel additives over Co–ReOₓ catalysts
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01315A, PaperXin Zhao, Hui Wang, Zhecheng Fang, Zixu Ma, Shuzhuang Sun, Dan Wu, Yongsheng Zhang, Charles Chunbao Xu, Shengyong Lu, Renfeng Nie, Jie Fu
Polyethylene terephthalate (PET) upcycling holds potential for producing aviation fuel additives such as benzene, toluene, and xylene (BTX), yet selectively activating C-O bonds over C-C bonds remains a formidable challenge....
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DOI: 10.1039/D5GC01315A, PaperXin Zhao, Hui Wang, Zhecheng Fang, Zixu Ma, Shuzhuang Sun, Dan Wu, Yongsheng Zhang, Charles Chunbao Xu, Shengyong Lu, Renfeng Nie, Jie Fu
Polyethylene terephthalate (PET) upcycling holds potential for producing aviation fuel additives such as benzene, toluene, and xylene (BTX), yet selectively activating C-O bonds over C-C bonds remains a formidable challenge....
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Oxygen-harvesting carbon dot photocatalysts for ambient tandem oxidative synthesis of quinazolin-4(3H)-ones
DOI: 10.1039/D5GC00962F, PaperBidyutjyoti Dutta, Bramhaiah Kommula, Kiran Kanwar, Ankur K. Guha, Ujjal K. Gautam, Diganta Sarma
An efficient photocatalytic route to one pot oxidative synthesis of quinazolin-4(3H)-ones using acidic and oxygenphilic waste derived carbon dots as an inexpensive metal-free photocatalyst cum oxidant.
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Advances in Paired Electrolysis for Furfural Conversion: From Design Principle, Mechanisms to Perspectives
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01306B, Critical ReviewZhikang Zhang, Jianan Li, Shuyi Yang, Tao E, Chong Peng
As a crucial biomass derivative, furfural can be converted into various high value-added chemicals in an environmentally friendly and efficient manner through electrocatalytic technology. Compared to individual anodic oxidation or...
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DOI: 10.1039/D5GC01306B, Critical ReviewZhikang Zhang, Jianan Li, Shuyi Yang, Tao E, Chong Peng
As a crucial biomass derivative, furfural can be converted into various high value-added chemicals in an environmentally friendly and efficient manner through electrocatalytic technology. Compared to individual anodic oxidation or...
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Techno-economic and life cycle analysis of bio-hydrogen production using bio-based waste streams through the integration of dark fermentation and microbial electrolysis
DOI: 10.1039/D4GC05020G, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Arna Ganguly, Pingping Sun, Xinyu Liu, Hernan E. Delgado, Lili Sun, Amgad ElgowainyBiowastes are produced daily. These wastes are rich in organic components with high potential to produce valuable products such as BioH2 and CO2. This study explores wastes converted into low-cost BioH2 through integrated processes.
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Soft Glass Interphase Engineering for Ultra-stable Aluminum Metal Batteries
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01118C, PaperShibin Zhang, Yan Xu, Danni Zhang, Lishun Bai, Yue Liu, Ying He, Feiyan Yu, Chengjun Liu, Sijie Li, Zhi Chang
Aluminum metal batteries (AMBs), a next-generation energy storage technology, have attracted significant attention due to aluminum's low cost, high theoretical capacity (2980 mAh/g), and inherent safety. However, unstable aluminum deposition...
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DOI: 10.1039/D5GC01118C, PaperShibin Zhang, Yan Xu, Danni Zhang, Lishun Bai, Yue Liu, Ying He, Feiyan Yu, Chengjun Liu, Sijie Li, Zhi Chang
Aluminum metal batteries (AMBs), a next-generation energy storage technology, have attracted significant attention due to aluminum's low cost, high theoretical capacity (2980 mAh/g), and inherent safety. However, unstable aluminum deposition...
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Green electrochemical synthesis of CeO2 nanopowders via an electrolysis–calcination process
DOI: 10.1039/D5GC01320H, CommunicationXiaohui Zhang, Xiaodong Liu, Xuan Xu, Kunyuan Zhao, Haifeng Sun, Peng Jing, Peng Xu, Baocang Liu, Jun Zhang
A green electrochemical strategy for CeO2 nanopowder synthesis, eliminating wastewater generation while offering a simple, controllable process.
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Highly Efficient Sulfurized Re-Ir Catalysts for Multiple N-Methylation of Ethylenediamine and Its Homologous Series with CO2 and H2 in Water Solvent
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01522G, Paper Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Min Wang, Mizuho Yabushita, Kazuki Okuma, Tomohiro Shono, Yoshinao Nakagawa, Keiichi Tomishige
Sulfurized Re-Ir clusters on a carbon black support were demonstrated to be highly active catalysts for the quadruple N-methylation of ethylenediamine (EDA) with CO2 and H2 to yield N,N,N’,N’-tetramethylethylenediamine (TetraM-EDA)....
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DOI: 10.1039/D5GC01522G, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Min Wang, Mizuho Yabushita, Kazuki Okuma, Tomohiro Shono, Yoshinao Nakagawa, Keiichi TomishigeSulfurized Re-Ir clusters on a carbon black support were demonstrated to be highly active catalysts for the quadruple N-methylation of ethylenediamine (EDA) with CO2 and H2 to yield N,N,N’,N’-tetramethylethylenediamine (TetraM-EDA)....
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Visible-light-induced selenium-mediated cascade cyclization of 2-isocyanobenzonitriles with secondary amines to access indole-fused polycyclics
DOI: 10.1039/D5GC01245G, PaperDongping Xu, Lizhen Jin, Mengya Huang, Wu Zhang
Controllable synthesis of indolo[2,3-b]quinoxalines and imidazo[4,5-b]indoles was achieved through the cascade cyclization of 2-isocyanobenzonitriles with secondary amines. An intramolecular EDA complex triggered this photochemical radical process.
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Aerobic Oxidation of Covalent Organic Framework Facilitating Photocatalytic CO2 Reduction with Water
Green Chem., 2025, Accepted Manuscript
DOI: 10.1039/D5GC01528F, PaperJiangqi Ning, Qing Niu, Zheyuan Liu, Liuyi Li
Photocatalytic CO2 reduction offers a promising approach for solar-to-chemical energy conversion. Achieving CO2 reduction under aerobic environment is challenging, primarily due to the competitive O2 reduction reaction on metal active...
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DOI: 10.1039/D5GC01528F, PaperJiangqi Ning, Qing Niu, Zheyuan Liu, Liuyi Li
Photocatalytic CO2 reduction offers a promising approach for solar-to-chemical energy conversion. Achieving CO2 reduction under aerobic environment is challenging, primarily due to the competitive O2 reduction reaction on metal active...
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Highly selective, catalyst-free CO2 reduction in strong acid without alkali cations by a mechanical energy-induced triboelectric plasma-electrolytic system
DOI: 10.1039/D5GC00977D, CommunicationHui Hu, Nannan Liu, Qinglong Ru, Wei Jiang, Yongcui Yang, Kailan Ma, Lixiang Meng, Zuliang Du, Bao Zhang, Gang Cheng
A mechanical energy-driven hybrid triboelectric plasma-electrochemical system in strong acids was constructed to trigger CO2 reduction at room temperature and atmospheric pressure without catalysts or alkali cations.
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Building a multifunctional Cu2Se@biomass carbon composite interfacial layer on a zinc anode for stable aqueous zinc-ion batteries
DOI: 10.1039/D5GC01034A, PaperWenjing Zheng, Tieran Zhou, Hao Zhou, Jie Guan, Fei Wang, Lin Zhu, Zhongti Sun, Kan Zhang
Cu2Se@BC was constructed to improve the structural stability of Zn anodes. It can induce the preferential orientation of zinc ions on the Zn (002) crystal plane. The AZIBs assembled with the Cu2Se@BC–Zn anode showed good electrochemical performance.
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Gentle and rapid synthesis of imine-linked covalent organic frameworks in acetic acid-based deep eutectic solvents
DOI: 10.1039/D5GC01800E, PaperQuanyuan Qiu, Guanwei Li, Chenxi Shi, Yueren Zeng, Kunchi Xie, Ke Wang, Zhen Song, Zhenjie Zhang, Xiaoqing Lin
Using natural green menthol/AA DES as both solvent and catalyst for the rapid synthesis of more than 20 highly crystalline imine-linked COFs with varying structures under mild conditions.
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Multidimensional metabolic engineering of Yarrowia lipolytica for highly efficient biosynthesis of betulinic acid
DOI: 10.1039/D5GC01276G, PaperXiaoyan Li, Liangcheng Jiao, Guowei Zhao, Yunchong Li, Yunjun Yan, Jinyong Yan
Yarrowia lipolytica was engineered for high-level betulinic acid production via modular pathway and organelle engineering, precursor and redox optimization, metabolic rewiring, and 3 L fermentation using cost-effective carbon sources.
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Water-assisted diboron activation: efficient synthesis of alkyl 1,2-bis(boronates) and 1,1,2-tris(boronates)
DOI: 10.1039/D5GC00743G, PaperKiran S. Patil, Shivakumar Reddappa, Maruti Suryavansi, Srinivasa Budagumpi, D. H. Nagaraju, Manoj V. Mane, Shubhankar Kumar Bose
A simple, efficient, and environmentally benign method for the synthesis of alkyl 1,2-bis(boronates) and 1,1,2-tris(boronates) from diboration and triboration of alkenes and alkynes has been developed via water-assisted diboron activation.
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Bio-waste derived Ni single-atom catalysts with Ni-pyridine-N4 active sites for efficient N-alkylation of alcohols and amines
DOI: 10.1039/D5GC00434A, PaperYuxin Zhu, Qiudi Zhu, Youjuan Tan, Hongqin Wang, Xuefei Liu, Wei Gong, Dongdong Ye, Xianglin Pei
Chitin derived from seafood waste is used as raw materials to fabricate Ni SACs. The synthetic catalyst exhibits excellent catalytic performance in N-alkylation of alcohols with amines, as well as good stability and broad substrate compatibility.
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Polymer monomers fabricated from biomass platform molecules over metal-free catalysts
DOI: 10.1039/D5GC01162K, PaperSiwei Xu, Nian Xiang, Jie He, Yang Li, Huankun Nie, Liang Huang, Chongbei Wu, Zehui Zhang
A biomass-derived carbon catalyst is reported to facilitate the synthesis of 2,5-furandicarboxylic acid and glycolic acid through the selective oxidation of 5-hydroxymethylfurfural and 1,3-dihydroxyacetone, respectively.
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Oxidized thiourea derivatives: uncovering new frontiers with resonant acoustic mixing (RAM)
DOI: 10.1039/D4GC06064D, PaperPietro Caboni, Francesco Basoccu, Shyamal Kanti Bera, Andrea Porcheddu
Nitrogen-containing compounds are essential for producing active pharmaceutical ingredients.
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Novel arylindane diols as sustainable primary antioxidants from lignin
DOI: 10.1039/D4GC05190D, Paper
Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Tessy Hendrickx, Laura Trullemans, Alexander J. Heyer, Imke Boonen, Marko Turkalj, Fatima Rammal, Yiqi Su, Besarta Matranxhi, Durgasruthi Pully, Bart Van Meerbeek, Peter Van Puyvelde, Marc Elskens, Kirsten L. Van Landuyt, Bert F. SelsA zeolite-catalyzed green synthesis of diisoeugenol. Together with diisoallylsyringol, these novel arylindane diols are safe and sustainable primary antioxidants.
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Electron-deficient Mo sites enhance electrochemical nitrate reduction to ammonia by promoting water dissociation
DOI: 10.1039/D5GC01249J, PaperXue Zhou, Wence Xu, Yunduo Huang, Zhonghui Gao, Yanqin Liang, Hui Jiang, Zhaoyang Li, Fang Wang, Shengli Zhu, Zhenduo Cui
Nanoporous Mo-doped Co2P exhibits outstanding NITRR performance, as the introduction of electron-deficient Mo promotes H2O dissociation to *H, enabling efficient NO hydrogenation with nearly 100% NH3 FE and 40.6% EE at −0.1 V vs. RHE.
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Synergism of tiny Ni clusters and Pt nanoparticles promoting efficient and stable electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis
DOI: 10.1039/D5GC00992H, PaperJie Huang, Min Tian, Liang Tong, Lihua Zhu, Lingling Li, Xianping Liao, Qingsheng Gao, Weizhen Wang, Zhiqing Yang, Tongxiang Liang, Hengqiang Ye
This work illustrates that the synergistic effect of tiny Nics and PtNPs provides a novel strategy for designing highly active and durable electrocatalysts (Pt10/Ni-ZrO2-NC) for the MOR, HER and the coupling reaction of MOR∥HER.
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